Stress-induced colouration and crosslinking of polymeric materials by mechanochemical formation of triphenylimidazolyl radicals.
نویسندگان
چکیده
Under mechanical stress, the hexaarylbiimidazole (HABI) motif can cleave to triphenylimidazolyl radicals when incorporated into a polymer matrix. The mechanically produced coloured radicals can initiate secondary radical reactions yielding polymer networks. Thus, the HABI mechanophore combines optical reporting of bond scission and reinforcement of polymers in a single molecular moiety.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 55 شماره
صفحات -
تاریخ انتشار 2016